Elements, Borides, Carbides, Hydrides
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Elements, Borides, Carbides, Hydrides / Elemente, Boride, Carbide, Hydride
Eisenmann, B. Publisher: Springer Verlag. Date of Publication: 18 December The discount is only available for 'Alert of Favourite Topics' newsletter recipients.
Elements, Borides, Carbides, Hydrides / Elemente, Boride, Carbide, Hydride. Authors: Eisenmann, B., Schäfer, H. Buy this book. Hardcover ,96 €. price for. Buy Elements, Borides, Carbides, Hydrides / Elemente, Boride, Carbide, Hydride (Landolt-Börnstein: Numerical Data and Functional Relationships in Science.
Click here to subscribe. Chemical compounds in which the relative number of atoms is not expressible as the ratio of small whole numbers, hence compounds for which the subscripts in the chemical formula are not rational for example, Cu 1. Sometimes they are called berthollide compounds to distinguish them from daltonides, in which the ratio of atoms is generally simple.
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The resulting materials are generally of variable composition, intensely colored, metallic or semiconducting, and different in chemical reactivity from the parent stoichiometric compounds from which they are derived. Nonstoichiometry is best known in the binary compounds of the transition elements, particularly the hydrides, oxides, chalcogenides, pnictides, carbides, and borides.
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It is also well represented in the so-called insertion or intercalation compounds, in which a metallic element or neutral molecule has been inserted in a stoichiometric host. Nonstoichiometric compounds are important in some solid-state devices such as rectifiers, thermoelectric generators, and photodetectors and are probably formed as chemical intermediates in many reactions involving solids for example, heterogeneous catalysis and metal corrosion.
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