Spillover and Mobility of Species on Solid Surfaces

Applied Catalysis A, General (v.202, #2)
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Biocatalysis in Oil Refining Inbunden. Inbunden Engelska, Spara som favorit. Skickas inom vardagar. This congress and its publication in the Studies on Surface Science and Catalysis series follow the tradition of previous conferences on spillover, initiated in Lyon, , and continued in Leipzig, , Kyoto and Dalian, For the fifth conference, held in S. Spillover is a process taking place during the interface of gas reactant molecules mainly hydrogen and oxygen on solid surfaces.

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However, different contributions to the more general area of the chemistry at surfaces, related with the mobility and migration of species, diffusion through membranes, fuel cell catalysts, etc. In fact the title of the present volume summarizes this attempt to extend the conference topics towards dynamics at surfaces.

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Preface by P Grange Contribution of spillover effects to heterogeneous catalysis by G. M Pajonk This paper, which is dedicated to Prof.

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Bernard Delmon for his outstanding contributions to heterogeneous catalysis, will only encompass his remarkable findings in the field of spillover phenomena. In a certain way, this paper is not a new additional review about spillover itself, i. Of course much will be described about the remote control concept but not exclusively.

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On the eve of the 5th International Conference on Spillover 5th ICSP to be held in Madrid in September , it is of particular interest to try getting a good picture of how the spillover-baby has grown up since its experimental discovery in the s. Keywords: Spillover; Heterogenous catalysis; Remote control;. Hydrogen spillover through the gas phase by E Baumgarten; L Maschke The only product, methane, was analyzed, using GC.

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In presence of catalyst the formation rate of methane was clearly above the limit of detection in contrast to measurements without catalyst. Different structure of the metal Pt, Ni, Rh, and Pt—Ni , obtained under helium or hydrogen lead to great differences in the reaction rates. Keywords: Spillover through the gasphase; Hydrogen spillover; Spillover and structure of metal crystallites;. The observed drop of the resistive part of a charge carrier relaxation process is attributed to the increase of mobile charges in the zeolite.

A Anderson; A Guerrero-Ruiz Catalytic activity measurements, infrared spectroscopic analysis and isotopic tracing experiments applied to the study of the surface hydroxyl groups of the supports have allowed different reaction mechanisms to be proposed on the bases of the detected surface species, their mobility, stability and reactivity.

The accumulation of carbon adspecies formed from methane decomposition on the metallic particles finally impedes carbon dioxide dissociation and induces rapid deactivation of this catalyst.

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The alumina support provides an alternate route for CO 2 activation by producing formate intermediates on its surface that subsequently decompose releasing CO. The proposed reaction pathway requires continuous surface mobility of species from the metal to the support and vice versa.

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It is shown that the two solids lead to the formation of the same adsorbed species: formate and carbonate species, in comparable superficial concentration. The methoxy groups are hydrogenated into methane by a process which probably involves a reverse spillover. Kinetic study of hydrogen adsorption on sulfated zirconia-supported platinum by N Satoh; J. Without Pt, the hydrogen uptake was scarcely appreciable.

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The rate could not be expressed by the rate equation derived on the assumption that the rate controlling step is the spillover step. Keywords: Sulfated zirconia; Hydrogen adsorption; Spillover; Surface diffusion;. In order to develop a CO oxidation catalyst exhibiting at a low-temperature range, an Rh-modified Cu-incorporated zeolite A catalyst was investigated.

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Purchase Spillover and Mobility of Species on Solid Surfaces, Volume - 1st Edition. Print Book & E-Book. ISBN , "Spillover and Mobility of Species and Solid Surfaces" collects the papers which were presented at the Fifth International Conference Spillover, either as oral or.

Supported 8. Another Cu—A was prepared by incorporation of Cu into the framework of zeolite A by using Cu nitrate in the mixed solution for crystallization. The reason of the results is ascribed to the oxygen spillover effect induced by the existence of Rh.